Equivalent Concept

IMPORTANT

Equivalent Concept: Overview

This topic covers concepts, such as, Normality, Equivalent Weight, Labelling of Oleum & Maximum and Minimum Sulphur Trioxide in Oleum etc.

Important Questions on Equivalent Concept

EASY
IMPORTANT

What is the  [OH]  in the final solution prepared by mixing 20.0 mL of 0.050 M HCl with 30.0 mL of 0.10  M Ba(OH)2 ?

EASY
IMPORTANT

The number of moles of KMn O 4 That will be needed to react with one mole of sulphite ion in acidic solution is

MEDIUM
IMPORTANT

What volume of oxygen gas (O2) measured at  0°C and 1 atm, is needed to burn completely 1L of propane gas  (C3H8) measured under the same conditions?

MEDIUM
IMPORTANT

The equivalent weight of   N a 2 S 2 O 3 .5 H 2 OandKBr O 3  In the following reactions would be:

  (i)2 S 2 O 3 2 + I 2 S 4 O 6 2 +2 I (ii)Br O 3 +6 H + +6 e B r +3 H 2 O

MEDIUM
IMPORTANT

The density of copper is  8.94 g ml1.  The number of coulombs needed to plate an area   10cm×10cm  to a thickness  102 cm using CuSO4 solution as electrolyte are:

MEDIUM
IMPORTANT

A 50 gm sample which may contain either H2SO4 or SO3 or  any combination of the two is mixed with 9 gm of water. The maximum oleum labelling possible of the sample formed can be :

HARD
IMPORTANT

If valence factor (n-factor) of compound NaHC2O4.2H2C2O4.3K2C2O4.4Al2C2O43.3FeC2O4 in acid-base titration is x and redox titration with KMnO4 is y, then y/x is

HARD
IMPORTANT

A metallic oxide contains 53% metal. The vapour density of the chloride of the metal is 66. Find the atomic weight of the metal.

MEDIUM
IMPORTANT

If 11.1 mg of CaCl2 and 12 mg of MgSO4 are present in  5 L of water, what is its degree of hardness?

MEDIUM
IMPORTANT

The amount of oxalic acid (eq.wt.63) required to prepare 500 ml of its 0.10 N solution is 

HARD
IMPORTANT

Find the equivalent weight of K2SO4·Al2(SO4)3· 24H2O (Mol. mass = M).

MEDIUM
IMPORTANT

Vapour density of a metal chloride is 66. Its oxide contains 53% metal. The atomic weight of the metal is

HARD
IMPORTANT

0.36 gm of a metal was dissolved in 100 ml of 1 N H2SO4, and the volume of solution was made upto 1000 ml by adding water. 40 ml of this solution were neutralized completely by 28 ml of 0.1N NaOH. The equivalent mass of the metal is

HARD
IMPORTANT

Vapour density of a metal chloride is 52.5. Calculate empirical formula of metal oxide if it contains 68% metal.

HARD
IMPORTANT

1.1 g CH3CH2nCOOH was burnt in excess of air and the resultant gases CO2+H2O were passed through a solution of NaOH. The resulting solution is divided into two equal parts. One part required 75 m.e. of HCl for neutralisation using phenolphthalein as indicator. The other part required 100 m.e. of HCl using methyl orange as indicator. Find n.

HARD
IMPORTANT

The molarity of H+ ions in a solution obtained by mixing 250 ml of 1N HCl, 250 ml of 0.5M H2SO4 and 500 ml of 2M HNO3 will be M. Then find the value of 10M.

HARD
IMPORTANT

Oxidation of K4FeCN6 by an oxidising agent is taking place to yield Fe3+CO2 and NO3-. If the K2Cr2O7 is oxidising agent, then how many moles of K2Cr2O7 reacts with 0.6 mole of K4FeCN6?

Round off the answer to the nearest integer.

MEDIUM
IMPORTANT

Find out the normality of a solution obtained by mixing 0.45 N KOH and 0.60 N NaOH in the ratio 2:1 by volume.

MEDIUM
IMPORTANT

Given that the oxidation number of sulphur is -2, the equivalent weight of sulphur is

MEDIUM
IMPORTANT

With 4 mole of Kl one mole of Cl2 is treated to yield gas, which is then treated with hypo solution, then correct regarding this is/are